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From the Rolls-Royce experimental archive: a quarter of a million communications from Rolls-Royce, 1906 to 1960's. Documents from the Sir Henry Royce Memorial Foundation (SHRMF).
Notes on the solidification and cooling of piston metal, detailing the effects of cooling rates on alloy structure.

Identifier  ExFiles\Box 76\3\  scan0004
Date  16th February 1916
  
Laboratory L529 contd page 3.
The effect of rate of cooling is also shown by X Y & Z, cooled slowly, rapidly & chilled respectively.
Tensile test-pieces are being made from part of Y & Z (will be reported later).
In the light of the cooling curves (with tin) the following stages may be noted during the solidification & cooling of piston metal.
(i) Solidification of Aluminum from various centres (the greater the number the more rapid the cooling) this occurs at 623°C (38°C lower than in the case of pure Aluminum). At 547°C the solid soltn of Copper & Aluminum changes to virtually pure copper & aluminum. If cooled rapidly the copper is retained to a large extent in solid solution. This gives a closer metal free of pores which is stronger mechanically & probably less liable to electrolytic action (see report L527).
  
  


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